DCPD:ENB 100:5 wt Postcure, Hermetic Lid

  • blank blank
Description:

Postcure of "95/5" or 100:5 wt DCPD:ENB with 4000:1:1 monomer:G2:TBP using hermetic lids (sealed pan); high-temperature exotherm likely due to oxidation or other radical chemistry.

Metadata

Name Value Last Modified
procedure
  • procedure:
    • Experiment Type: Liquid_CureKinetics_12Cmin
    • Sample Name: ZM-1-27-06_100-5_DCPD-ENB_hermetic_curekinetics_5Cmin
    • Sample Mass (mg): 6.150 mg
    • Reference Pan Type: Tzero Aluminum Hermetic
    • Run Date: 6/27/2023 3:09:48 PM
    • Operator: ZM
    • Instrument Name: DSC2A-01089
    • Instrument Type: DSC250
    • Serial Number: DSC2A-01089
    • Location of Instrument: Manufacturing Test
    • Trios version: 5.0.0.44608
    • Ramp rate (°C/min): 5.0
    • Ramp Min Temp (°C): 5.0
    • Ramp Max Temp (°C): 200.0
  • Analysis:
    • Max Heat Flow: -0.1
    • Min Baseline Temp: 152.41
    • Max Baseline Temp: 172.245
    • Glass transition temperature: 163.612
Extracted by https://re-mat.clowder.ncsa.illinois.edu/api/extractors/remat.parameters.from_txt on Aug 18, 2023
Batch ID
  • Batch ID: 27-6-2023 15:09 ZM
  • procedure:
    • Operator Initials: ZM
    • Run Date and Time: 2023-06-27 15:09:48
    • Time to DSC (mins after adding catalyst): n/a
    • Ambient temperature (°C): 21
    • Relative Humidity (%): 65
    • null: null
    • Storage time - postcure (hrs): 72
    • Storage Temperature (°C): 21
    • Storage condition: N2
    • Storage location: plastic bag
    • Polymerization method: FROMP
    • Polymerization geometry: glass slides
    • Polymerization Date and Time: 2023-06-21 00:00:00
    • Initiation method: Thermal, soldering iron
    • Initiation temperature (°C): null
  • inputs:
    • monomers:
        • name: DCPD
        • SMILES: C1C=CC2C1C3CC2C=C3
        • Measured mass (g): 3.81
        • Measured volume (μL): -
        • Prepared in glovebox?: no
        • Preparation temperature (°C): 21
        • Computed mass (g): 3.81
        • Molecular Weight: 132.2
        • Moles: 0.03
        • Monomer mol%: 94.8
        • name: ENB
        • SMILES: CC=C1CC2CC1C=C2
        • Measured mass (g): 0.19
        • Measured volume (μL): -
        • Prepared in glovebox?: no
        • Preparation temperature (°C): 21
        • Computed mass (g): 0.19
        • Molecular Weight: 120.2
        • Moles: 0.0
        • Monomer mol%: 5.2
    • catalysts:
        • name: GC-2
        • SMILES: CC1=CC(=C(C(=C1)C)N2CCN(C2=[Ru](=CC3=CC=CC=C3)(Cl)Cl)C4=C(C=C(C=C4C)C)C)C.C1CCC(CC1)P(C2CCCCC2)C3CCCCC3
        • Measured mass (mg): 6.46
        • Computed mass (g): 0.00646
        • Prepared in glovebox?: no
        • Preparation temperature (°C): 21
        • Molecular Weight: 848.98
        • Moles: 0.0
        • Monomer:Catalyst molar ratio: 3995.29
    • inhibitors:
        • name: TBP
        • SMILES: CCCCOP(=O)(OCCCC)OCCCC
        • Measured volume (μL): 2.05
        • Prepared in glovebox?: -
        • Preparation temperature (°C): -
        • Density: 0.925
        • Computed mass (mg): 1.89625
        • Molecular Weight: 250.3
        • Moles: 0.01
        • Inhibitor:Catalyst molar ratio: 995.63
    • additives:
    • solvents:
Extracted by https://re-mat.clowder.ncsa.illinois.edu/api/extractors/remat.experiment.from_excel on Aug 18, 2023
  • procedure:
    • Experiment Type: Liquid_CureKinetics_12Cmin
    • Sample Name: ZM-1-27-06_100-5_DCPD-ENB_hermetic_curekinetics_5Cmin
    • Sample Mass (mg): 6.150 mg
    • Reference Pan Type: Tzero Aluminum Hermetic
    • Run Date: 6/27/2023 3:09:48 PM
    • Operator: ZM
    • Instrument Name: DSC2A-01089
    • Instrument Type: DSC250
    • Serial Number: DSC2A-01089
    • Location of Instrument: Manufacturing Test
    • Trios version: 5.0.0.44608
    • Ramp rate (°C/min): 5.0
    • Ramp Min Temp (°C): 5.0
    • Ramp Max Temp (°C): 200.0
  • Analysis:
    • Max Heat Flow: -0.1
    • Min Baseline Temp: 152.41
    • Max Baseline Temp: 172.245
    • Glass transition temperature: 163.612
  • Batch ID: 27-6-2023 15:09 ZM
  • procedure:
    • Operator Initials: ZM
    • Run Date and Time: 2023-06-27 15:09:48
    • Time to DSC (mins after adding catalyst): n/a
    • Ambient temperature (°C): 21
    • Relative Humidity (%): 65
    • null: null
    • Storage time - postcure (hrs): 72
    • Storage Temperature (°C): 21
    • Storage condition: N2
    • Storage location: plastic bag
    • Polymerization method: FROMP
    • Polymerization geometry: glass slides
    • Polymerization Date and Time: 2023-06-21 00:00:00
    • Initiation method: Thermal, soldering iron
    • Initiation temperature (°C): null
  • inputs:
    • monomers:
        • name: DCPD
        • SMILES: C1C=CC2C1C3CC2C=C3
        • Measured mass (g): 3.81
        • Measured volume (μL): -
        • Prepared in glovebox?: no
        • Preparation temperature (°C): 21
        • Computed mass (g): 3.81
        • Molecular Weight: 132.2
        • Moles: 0.03
        • Monomer mol%: 94.8
        • name: ENB
        • SMILES: CC=C1CC2CC1C=C2
        • Measured mass (g): 0.19
        • Measured volume (μL): -
        • Prepared in glovebox?: no
        • Preparation temperature (°C): 21
        • Computed mass (g): 0.19
        • Molecular Weight: 120.2
        • Moles: 0.0
        • Monomer mol%: 5.2
    • catalysts:
        • name: GC-2
        • SMILES: CC1=CC(=C(C(=C1)C)N2CCN(C2=[Ru](=CC3=CC=CC=C3)(Cl)Cl)C4=C(C=C(C=C4C)C)C)C.C1CCC(CC1)P(C2CCCCC2)C3CCCCC3
        • Measured mass (mg): 6.46
        • Computed mass (g): 0.00646
        • Prepared in glovebox?: no
        • Preparation temperature (°C): 21
        • Molecular Weight: 848.98
        • Moles: 0.0
        • Monomer:Catalyst molar ratio: 3995.29
    • inhibitors:
        • name: TBP
        • SMILES: CCCCOP(=O)(OCCCC)OCCCC
        • Measured volume (μL): 2.05
        • Prepared in glovebox?: -
        • Preparation temperature (°C): -
        • Density: 0.925
        • Computed mass (mg): 1.89625
        • Molecular Weight: 250.3
        • Moles: 0.01
        • Inhibitor:Catalyst molar ratio: 995.63
    • additives:
    • solvents:
Extractor Started Latest Update Latest Status
Submission Status
Timestamp Status Message
Fri Aug 18 21:54:01 UTC 2023 PROCESS: Uploading dataset metadata.
Submission Status
Timestamp Status Message
Fri Aug 18 21:53:59 UTC 2023 PROCESS: Uploading dataset metadata.

Statistics

Views: 57
Last viewed: Jun 06, 2025 17:50:23
Downloads: 0
Last downloaded: Never
Last Modified: Apr 29, 2025 14:25:47

Spaces containing the Dataset

Collections containing the Dataset

Tags