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Chem Activation, THF-3-I, AC-1-122-04-2, Post Cure

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Anna Cramblitt
Description:

8000:1:1 DCPD/ENB 100/5 wt. Chemical activation with G3-H in THF. Sampled close to initiation (I).

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Metadata

Name Value Last Modified
procedure
  • procedure:
    • Experiment Type: LMD_DCPD_POST_CURE
    • Sample Name: ACC-1-122-04-2_THF_I_postcure
    • Sample Mass (mg): 9.490 mg
    • Reference Pan Type: Tzero Aluminum
    • Run Date: 2/15/2023 5:06:42 PM
    • Operator: ACC
    • Instrument Name: DSC2A-01089
    • Instrument Type: DSC250
    • Serial Number: DSC2A-01089
    • Location of Instrument: Manufacturing Test
    • Trios version: 5.0.0.44608
    • Ramp rate (°C/min): 10.0
    • Ramp Min Temp (°C): -20.0
    • Ramp Max Temp (°C): 250.0
  • Analysis:
    • Max Heat Flow: 3.23
    • Min Baseline Temp: 138.848
    • Max Baseline Temp: 197.287
    • Glass transition temperature: 165.414
Extracted by https://re-mat.clowder.ncsa.illinois.edu/api/extractors/remat.parameters.from_txt on Apr 25, 2025
Batch ID
  • Batch ID: 02-2-2023 00:00 AC
  • procedure:
    • general:
      • Operator Initials: AC
      • Mix Date and Time: 2023-02-02 00:00:00
      • Polymerization Date and Time: 2023-02-02 00:00:00
      • Resin Storage Temperature (°C): null
      • Resin Storage atmosphere: null
      • Resin Storage location: null
      • Polymer Storage Temperature (°C): null
      • Polymer Storage armosphere: null
      • Polymer Storage location: null
      • Mixing Conditions: null
      • Mixing Type: Sonication
      • Mixing Time (min): 2
      • Preparation temperature (°C): 21
      • Use Glovebox: NO
      • Polymerization: null
      • Type of polymerization: FROMP
      • Ambient temperature (°C): 21
      • Resin temperaure at the start of polymerization (°C): null
      • Select Geometry from geometries tab: null
      • Geometry - Select from library: TUBE-3
      • Resin height (mm): 32
      • Diameter (mm): 9.74
      • Thickness (mm): 0.52
      • Tube length (mm): 77.96
      • Post Cure Sampling Location: Top
      • Empty-dim: null
      • Initiation: null
      • Initiation method: CHEMICAL
      • Photocontrol: null
      • Photocontrol?: NO
      • null: null
    • chemical initiation:
      • initiator-catalyst-solvent-concentration-mg/microL: 66.66666666666667
      • initiator-catalyst-solvent-concentration-moles/L: 9.173259947253755E-9
      • initiator-inputs:
          • name: GC-3 (Grubbs Catalyst gen-3 H-substituted)
          • SMILES: Cl[Ru](=C1N(C2=C(C)C=C(C)C=C2C)CCN1C3=C(C)C=C(C)C=C3C)([N]4=CC=CC=C4)(Cl)([N]5=CC=CC=C5)=CC6=CC=CC=C6
          • Role: Catalyst
          • Measured mass (mg): 5
          • Measured volume (μL): null
          • Molecular Weight: 726.75
          • Moles: 6.88e-03
          • name: tetrahydrofuran (THF)
          • SMILES: C1CCOC1
          • Role: Solvent
          • Measured mass (mg): null
          • Measured volume (μL): 75
          • Molecular Weight: 72.107
          • Moles: 0.00e+00
      • initiator-procedure:
        • Prepared in GloveBox?: NO
        • Preparation temperature (°C): RT
        • Mixing type: Sonication
        • Mixing time (mins): 1
        • Total volume used for initiation (μL): 10
  • inputs:
    • monomers:
      • monomer-inputs:
          • name: Ethylidene Norbornene (ENB)
          • SMILES: CC=C1CC2CC1C=C2
          • Measured mass (g): 0.37
          • Measured volume (μL): null
          • Computed mass (g): 0.37
          • Molecular Weight: 120.2
          • Moles: 3.08e-03
          • Monomer mol%: 5.17
          • name: Dicyclopentadiene (DCPD)
          • SMILES: C1C=CC2C1C3CC2C=C3
          • Measured mass (g): 7.47
          • Measured volume (μL): null
          • Computed mass (g): 7.47
          • Molecular Weight: 132.2
          • Moles: 5.65e-02
          • Monomer mol%: 94.83
      • monomer-procedure:
        • Prepared in GloveBox?: NO
        • Preparation temperature (°C): RT
        • Mixing type: N/A
        • Mixing time (mins): null
    • catalysts:
      • catalyst-inputs:
          • name: GC-2
          • SMILES: CC1=CC(=C(C(=C1)C)N2CCN(C2=[Ru](=CC3=CC=CC=C3)(Cl)Cl)C4=C(C=C(C=C4C)C)C)C.C1CCC(CC1)P(C2CCCCC2)C3CCCCC3
          • Measured mass (mg): 6.28
          • Computed mass (g): 0.00628
          • Molecular Weight: 848.98
          • Moles: 7.40e-06
          • Monomer:Catalyst molar ratio: 8054.97
      • catalyst-procedure:
        • Prepared in GloveBox?: NO
        • Preparation temperature (°C): RT
        • Mixing type: Sonication
        • Mixing time (mins): 3
    • inhibitors:
      • inhibitor-inputs:
          • name: TBP
          • SMILES: CCCCOP(=O)(OCCCC)OCCCC
          • Measured volume (μL): 2
          • Density: 0.925
          • Computed mass (mg): 0.00185
          • Molecular Weight: 250.3
          • Moles: 7.39e-06
          • Inhibitor:Catalyst molar ratio: 1.0
      • inhibitor-procedure:
        • Prepared in GloveBox?: NO
        • Preparation temperature (°C): null
        • Mixing type: N/A
        • Mixing time (mins): null
    • additives:
      • additive-inputs:
      • additive-procedure:
        • Prepared in GloveBox?: NO
        • Preparation temperature (°C): null
        • Mixing type: N/A
        • Mixing time (mins): null
    • solvents:
      • solvent-inputs:
      • solvent-procedure:
        • Prepared in GloveBox?: NO
        • Preparation temperature (°C): null
        • Mixing type: N/A
        • Mixing time (mins): null
  • FROMP Measurements:
    • Measured frontal velocity (mm/s): 1.13
    • Measured frontal velocity with light exposure (mm/s): null
    • Measured maximum temperature (°C): 221.351
    • Type of front: LINEAR
Extracted by https://re-mat.clowder.ncsa.illinois.edu/api/extractors/remat.experiment.from_excel on Apr 25, 2025
  • procedure:
    • Experiment Type: LMD_DCPD_POST_CURE
    • Sample Name: ACC-1-122-04-2_THF_I_postcure
    • Sample Mass (mg): 9.490 mg
    • Reference Pan Type: Tzero Aluminum
    • Run Date: 2/15/2023 5:06:42 PM
    • Operator: ACC
    • Instrument Name: DSC2A-01089
    • Instrument Type: DSC250
    • Serial Number: DSC2A-01089
    • Location of Instrument: Manufacturing Test
    • Trios version: 5.0.0.44608
    • Ramp rate (°C/min): 10.0
    • Ramp Min Temp (°C): -20.0
    • Ramp Max Temp (°C): 250.0
  • Analysis:
    • Max Heat Flow: 3.23
    • Min Baseline Temp: 138.848
    • Max Baseline Temp: 197.287
    • Glass transition temperature: 165.414
  • Batch ID: 02-2-2023 00:00 AC
  • procedure:
    • general:
      • Operator Initials: AC
      • Mix Date and Time: 2023-02-02 00:00:00
      • Polymerization Date and Time: 2023-02-02 00:00:00
      • Resin Storage Temperature (°C): null
      • Resin Storage atmosphere: null
      • Resin Storage location: null
      • Polymer Storage Temperature (°C): null
      • Polymer Storage armosphere: null
      • Polymer Storage location: null
      • Mixing Conditions: null
      • Mixing Type: Sonication
      • Mixing Time (min): 2
      • Preparation temperature (°C): 21
      • Use Glovebox: NO
      • Polymerization: null
      • Type of polymerization: FROMP
      • Ambient temperature (°C): 21
      • Resin temperaure at the start of polymerization (°C): null
      • Select Geometry from geometries tab: null
      • Geometry - Select from library: TUBE-3
      • Resin height (mm): 32
      • Diameter (mm): 9.74
      • Thickness (mm): 0.52
      • Tube length (mm): 77.96
      • Post Cure Sampling Location: Top
      • Empty-dim: null
      • Initiation: null
      • Initiation method: CHEMICAL
      • Photocontrol: null
      • Photocontrol?: NO
      • null: null
    • chemical initiation:
      • initiator-catalyst-solvent-concentration-mg/microL: 66.66666666666667
      • initiator-catalyst-solvent-concentration-moles/L: 9.173259947253755E-9
      • initiator-inputs:
          • name: GC-3 (Grubbs Catalyst gen-3 H-substituted)
          • SMILES: Cl[Ru](=C1N(C2=C(C)C=C(C)C=C2C)CCN1C3=C(C)C=C(C)C=C3C)([N]4=CC=CC=C4)(Cl)([N]5=CC=CC=C5)=CC6=CC=CC=C6
          • Role: Catalyst
          • Measured mass (mg): 5
          • Measured volume (μL): null
          • Molecular Weight: 726.75
          • Moles: 6.88e-03
          • name: tetrahydrofuran (THF)
          • SMILES: C1CCOC1
          • Role: Solvent
          • Measured mass (mg): null
          • Measured volume (μL): 75
          • Molecular Weight: 72.107
          • Moles: 0.00e+00
      • initiator-procedure:
        • Prepared in GloveBox?: NO
        • Preparation temperature (°C): RT
        • Mixing type: Sonication
        • Mixing time (mins): 1
        • Total volume used for initiation (μL): 10
  • inputs:
    • monomers:
      • monomer-inputs:
          • name: Ethylidene Norbornene (ENB)
          • SMILES: CC=C1CC2CC1C=C2
          • Measured mass (g): 0.37
          • Measured volume (μL): null
          • Computed mass (g): 0.37
          • Molecular Weight: 120.2
          • Moles: 3.08e-03
          • Monomer mol%: 5.17
          • name: Dicyclopentadiene (DCPD)
          • SMILES: C1C=CC2C1C3CC2C=C3
          • Measured mass (g): 7.47
          • Measured volume (μL): null
          • Computed mass (g): 7.47
          • Molecular Weight: 132.2
          • Moles: 5.65e-02
          • Monomer mol%: 94.83
      • monomer-procedure:
        • Prepared in GloveBox?: NO
        • Preparation temperature (°C): RT
        • Mixing type: N/A
        • Mixing time (mins): null
    • catalysts:
      • catalyst-inputs:
          • name: GC-2
          • SMILES: CC1=CC(=C(C(=C1)C)N2CCN(C2=[Ru](=CC3=CC=CC=C3)(Cl)Cl)C4=C(C=C(C=C4C)C)C)C.C1CCC(CC1)P(C2CCCCC2)C3CCCCC3
          • Measured mass (mg): 6.28
          • Computed mass (g): 0.00628
          • Molecular Weight: 848.98
          • Moles: 7.40e-06
          • Monomer:Catalyst molar ratio: 8054.97
      • catalyst-procedure:
        • Prepared in GloveBox?: NO
        • Preparation temperature (°C): RT
        • Mixing type: Sonication
        • Mixing time (mins): 3
    • inhibitors:
      • inhibitor-inputs:
          • name: TBP
          • SMILES: CCCCOP(=O)(OCCCC)OCCCC
          • Measured volume (μL): 2
          • Density: 0.925
          • Computed mass (mg): 0.00185
          • Molecular Weight: 250.3
          • Moles: 7.39e-06
          • Inhibitor:Catalyst molar ratio: 1.0
      • inhibitor-procedure:
        • Prepared in GloveBox?: NO
        • Preparation temperature (°C): null
        • Mixing type: N/A
        • Mixing time (mins): null
    • additives:
      • additive-inputs:
      • additive-procedure:
        • Prepared in GloveBox?: NO
        • Preparation temperature (°C): null
        • Mixing type: N/A
        • Mixing time (mins): null
    • solvents:
      • solvent-inputs:
      • solvent-procedure:
        • Prepared in GloveBox?: NO
        • Preparation temperature (°C): null
        • Mixing type: N/A
        • Mixing time (mins): null
  • FROMP Measurements:
    • Measured frontal velocity (mm/s): 1.13
    • Measured frontal velocity with light exposure (mm/s): null
    • Measured maximum temperature (°C): 221.351
    • Type of front: LINEAR
Extractor Started Latest Update Latest Status
Submission Status
Timestamp Status Message
Fri Apr 25 19:39:18 UTC 2025 PROCESS: Uploading dataset metadata.
Submission Status
Timestamp Status Message
Fri Apr 25 19:37:49 UTC 2025 PROCESS: Uploading dataset metadata.

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Last viewed: Jun 15, 2025 02:53:25
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Last Modified: May 05, 2025 20:31:04

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