Clowder
  1. Rheometry
  2. 2025-10-28 Line...

2025-10-28 Linear viscoelasticity of quenched DCPD resin

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Description:

linear viscoelastic measurements of DCPD that has been ROMPed to above the printability state and then quenched with the addition of EVE which binds to the catalyst. These tests reveal minimal mutation over the duration of the test after adding 500 eq of EVE to GC2 by molecular weight. However, tests later revealed that ROMP continued happening over the order of weeks meaning that the 500 eq of EVE was not sufficient to completely stop ROMP. Frequency sweep tests reveal a power law behavior in the low frequency (terminal) regime. Creep tests reveal minimal mutation between tests

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Metadata

Name Value Last Modified
Batch ID
  • Batch ID: 25-10-2025 00:00 MCM
  • procedure:
    • general:
      • Operator Initials: MCM
      • Mix Date and Time: 2025-10-25 00:00:00
      • Polymerization Date and Time: 2025-10-28 00:00:00
      • Resin Storage Temperature (°C): null
      • Resin Storage atmosphere: null
      • Resin Storage location: null
      • Polymer Storage Temperature (°C): null
      • Polymer Storage armosphere: null
      • Polymer Storage location: null
      • Mixing Conditions: null
      • Mixing Type: Sonication
      • Mixing Time (min): null
      • Preparation temperature (°C): null
      • Use Glovebox: NO
      • Polymerization: null
      • Type of polymerization: ROMP
      • Ambient temperature (°C): null
      • Resin temperaure at the start of polymerization (°C): null
      • Select Geometry from geometries tab: null
      • Geometry - Select from library: null
      • #N/A: null
      • Initiation: null
      • Initiation method: THERMAL
      • Photocontrol: null
      • Photocontrol?: NO
      • null: null
    • thermal initiation:
      • Heat Source: SOLDERING IRON
      • Heat Source Name: null
      • Heater diameter (mm): null
      • Submerged length (mm): null
      • Power (W): null
      • Voltage (V): null
      • Current (A): null
      • Heat source temperature (°C): null
      • Induction time (s): null
  • inputs:
    • monomers:
      • monomer-inputs:
          • name: Ethylidene Norbornene (ENB)
          • SMILES: CC=C1CC2CC1C=C2
          • Measured mass (g): 0.0913373860182371
          • Measured volume (μL): null
          • Computed mass (g): 0.0913373860182371
          • Molecular Weight (g/mol): 120.2
          • Moles: 7.60e-04
          • Monomer mol%: 5.0
          • name: Dicyclopentadiene (DCPD)
          • SMILES: C1C=CC2C1C3CC2C=C3
          • Measured mass (g): 1.9086626139817628
          • Measured volume (μL): null
          • Computed mass (g): 1.9086626139817628
          • Molecular Weight (g/mol): 132.2
          • Moles: 1.44e-02
          • Monomer mol%: 95.0
      • monomer-procedure:
        • Prepared in GloveBox?: NO
        • Preparation temperature (°C): null
        • Mixing type: N/A
        • Mixing time (mins): null
    • catalysts:
      • catalyst-inputs:
          • name: GC-2
          • SMILES: CC1=CC(=C(C(=C1)C)N2CCN(C2=[Ru](=CC3=CC=CC=C3)(Cl)Cl)C4=C(C=C(C=C4C)C)C)C.C1CCC(CC1)P(C2CCCCC2)C3CCCCC3
          • Measured mass (mg): 12.9
          • Computed mass (g): 0.0129
          • Molecular Weight (g/mol): 848.98
          • Moles: 1.52e-05
          • Monomer:Catalyst molar ratio: 1000.19
      • catalyst-procedure:
        • Prepared in GloveBox?: NO
        • Preparation temperature (°C): null
        • Mixing type: Sonication
        • Mixing time (mins): null
    • inhibitors:
      • inhibitor-inputs:
          • name: TBP
          • SMILES: CCCCOP(=O)(OCCCC)OCCCC
          • Measured volume (μL): 4.1
          • Density: 0.925
          • Computed mass (g): 0.0037925
          • Molecular Weight (g/mol): 250.3
          • Moles: 1.52e-05
          • Inhibitor:Catalyst molar ratio: 1.0
      • inhibitor-procedure:
        • Prepared in GloveBox?: NO
        • Preparation temperature (°C): null
        • Mixing type: N/A
        • Mixing time (mins): null
    • additives:
      • additive-inputs:
      • additive-procedure:
        • Prepared in GloveBox?: NO
        • Preparation temperature (°C): null
        • Mixing type: N/A
        • Mixing time (mins): null
    • solvents:
      • solvent-inputs:
      • solvent-procedure:
        • Prepared in GloveBox?: NO
        • Preparation temperature (°C): null
        • Mixing type: N/A
        • Mixing time (mins): null
Extracted by https://re-mat.clowder.ncsa.illinois.edu/api/extractors/remat.experiment.from_excel on Jan 28, 2026
  • Batch ID: 25-10-2025 00:00 MCM
  • procedure:
    • general:
      • Operator Initials: MCM
      • Mix Date and Time: 2025-10-25 00:00:00
      • Polymerization Date and Time: 2025-10-28 00:00:00
      • Resin Storage Temperature (°C): null
      • Resin Storage atmosphere: null
      • Resin Storage location: null
      • Polymer Storage Temperature (°C): null
      • Polymer Storage armosphere: null
      • Polymer Storage location: null
      • Mixing Conditions: null
      • Mixing Type: Sonication
      • Mixing Time (min): null
      • Preparation temperature (°C): null
      • Use Glovebox: NO
      • Polymerization: null
      • Type of polymerization: ROMP
      • Ambient temperature (°C): null
      • Resin temperaure at the start of polymerization (°C): null
      • Select Geometry from geometries tab: null
      • Geometry - Select from library: null
      • #N/A: null
      • Initiation: null
      • Initiation method: THERMAL
      • Photocontrol: null
      • Photocontrol?: NO
      • null: null
    • thermal initiation:
      • Heat Source: SOLDERING IRON
      • Heat Source Name: null
      • Heater diameter (mm): null
      • Submerged length (mm): null
      • Power (W): null
      • Voltage (V): null
      • Current (A): null
      • Heat source temperature (°C): null
      • Induction time (s): null
  • inputs:
    • monomers:
      • monomer-inputs:
          • name: Ethylidene Norbornene (ENB)
          • SMILES: CC=C1CC2CC1C=C2
          • Measured mass (g): 0.0913373860182371
          • Measured volume (μL): null
          • Computed mass (g): 0.0913373860182371
          • Molecular Weight (g/mol): 120.2
          • Moles: 7.60e-04
          • Monomer mol%: 5.0
          • name: Dicyclopentadiene (DCPD)
          • SMILES: C1C=CC2C1C3CC2C=C3
          • Measured mass (g): 1.9086626139817628
          • Measured volume (μL): null
          • Computed mass (g): 1.9086626139817628
          • Molecular Weight (g/mol): 132.2
          • Moles: 1.44e-02
          • Monomer mol%: 95.0
      • monomer-procedure:
        • Prepared in GloveBox?: NO
        • Preparation temperature (°C): null
        • Mixing type: N/A
        • Mixing time (mins): null
    • catalysts:
      • catalyst-inputs:
          • name: GC-2
          • SMILES: CC1=CC(=C(C(=C1)C)N2CCN(C2=[Ru](=CC3=CC=CC=C3)(Cl)Cl)C4=C(C=C(C=C4C)C)C)C.C1CCC(CC1)P(C2CCCCC2)C3CCCCC3
          • Measured mass (mg): 12.9
          • Computed mass (g): 0.0129
          • Molecular Weight (g/mol): 848.98
          • Moles: 1.52e-05
          • Monomer:Catalyst molar ratio: 1000.19
      • catalyst-procedure:
        • Prepared in GloveBox?: NO
        • Preparation temperature (°C): null
        • Mixing type: Sonication
        • Mixing time (mins): null
    • inhibitors:
      • inhibitor-inputs:
          • name: TBP
          • SMILES: CCCCOP(=O)(OCCCC)OCCCC
          • Measured volume (μL): 4.1
          • Density: 0.925
          • Computed mass (g): 0.0037925
          • Molecular Weight (g/mol): 250.3
          • Moles: 1.52e-05
          • Inhibitor:Catalyst molar ratio: 1.0
      • inhibitor-procedure:
        • Prepared in GloveBox?: NO
        • Preparation temperature (°C): null
        • Mixing type: N/A
        • Mixing time (mins): null
    • additives:
      • additive-inputs:
      • additive-procedure:
        • Prepared in GloveBox?: NO
        • Preparation temperature (°C): null
        • Mixing type: N/A
        • Mixing time (mins): null
    • solvents:
      • solvent-inputs:
      • solvent-procedure:
        • Prepared in GloveBox?: NO
        • Preparation temperature (°C): null
        • Mixing type: N/A
        • Mixing time (mins): null
Extractor Started Latest Update Latest Status
Submission Status
Timestamp Status Message
Wed Jan 28 22:31:00 UTC 2026 PROCESS: Uploading dataset metadata.

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Last viewed: Jan 29, 2026 07:22:33
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Last Modified: Jan 02, 2026 21:50:45

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